Process can use coal, shale gas and biomass while consuming carbon dioxide
Engineers at The Ohio State University are developing technologies that have the potential to economically convert fossil fuels and biomass into useful products including electricity without emitting carbon dioxide to the atmosphere.
In the first of two papers published in the journal Energy & Environmental Science, the engineers report that they’ve devised a process that transforms shale gas into products such as methanol and gasoline—all while consuming carbon dioxide. This process can also be applied to coal and biomass to produce useful products.
In the second paper, they report that they’ve found a way to greatly extend the lifetime of the particles that enable the chemical reaction to transform coal or other fuels to electricity and useful products over a length of time that is useful for commercial operation.Under certain conditions, the technology consumes all the carbon dioxide it produces plus additional carbon dioxide from an outside source.
Finally, the same team has discovered and patented a way with the potential to lower the capital costs in producing a fuel gas called synthesis gas, or “syngas,” by about 50 percent over the traditional technology.
The technology, known as chemical looping, uses metal oxide particles in high-pressure reactors to “burn” fossil fuels and biomass without the presence of oxygen in the air. The metal oxide provides the oxygen for the reaction.
Chemical looping is capable of acting as a stopgap technology that can provide clean electricity until renewable energies such as solar and wind become both widely available and affordable, the engineers said.
“Renewables are the future,” said Liang-Shih Fan, Distinguished University Professor in Chemical and Biomolecular Engineering, who leads the effort. “We need a bridge that allows us to create clean energy until we get there—something affordable we can use for the next 30 years or more, while wind and solar power become the prevailing technologies.”
Five years ago, Fan and his research team demonstrated a technology called coal-direct chemical looping (CDCL) combustion, in which they were able to release energy from coal while capturing more than 99 percent of the resulting carbon dioxide, preventing its emission to the environment. The key advance of CDCL came in the form of iron oxide particles which supply the oxygen for chemical combustion in a moving bed reactor. After combustion, the particles take back the oxygen from air, and the cycle begins again.
The challenge then, as now, was how to keep the particles from wearing out, said Andrew Tong, research assistant professor of chemical and biomolecular engineering at Ohio State.
While five years ago the particles for CDCL lasted through 100 cycles for more than eight days of continuous operation, the engineers have since developed a new formulation that lasts for more than 3,000 cycles, or more than eight months of continuous use in laboratory tests. A similar formulation has also been tested at sub-pilot and pilot plants.
“The particle itself is a vessel, and it’s carrying the oxygen back and forth in this process, and it eventually falls apart. Like a truck transporting goods on a highway, eventually it’s going to undergo some wear and tear. And we’re saying we devised a particle that can make the trip 3,000 times in the lab and still maintain its integrity,” Tong said.
This is the longest lifetime ever reported for the oxygen carrier, he added. The next step is to test the carrier in an integrated coal-fired chemical looping process.
Another advancement involves the engineers’ development of chemical looping for production of syngas, which in turn provides the building blocks for a host of other useful products including ammonia, plastics or even carbon fibers.
This is where the technology really gets interesting: It provides a potential industrial use for carbon dioxide as a raw material for producing useful, everyday products.
Today, when carbon dioxide is scrubbed from power plant exhaust, it is intended to be buried to keep it from entering the atmosphere as a greenhouse gas. In this new scenario, some of the scrubbed carbon dioxide wouldn’t need to be buried; it could be converted into useful products.
Taken together, Fan said, these advancements bring Ohio State’s chemical looping technology many steps closer to commercialization.
He calls the most recent advances “significant and exciting,” and they’ve been a long time coming. True innovations in science are uncommon, and when they do happen, they’re not sudden. They’re usually the result of decades of concerted effort—or, in Fan’s case, the result of 40 years of research at Ohio State. Throughout some of that time, his work has been supported by the U.S. Department of Energy and the Ohio Development Services Agency.
“This is my life’s work,” Fan said.
Learn more: A fossil fuel technology that doesn’t pollute
The Latest on: Chemical looping
[google_news title=”” keyword=”chemical looping” num_posts=”10″ blurb_length=”0″ show_thumb=”left”]- What’s the best way to deal with hard-to-recycle plastics?on May 8, 2024 at 10:01 pm
Around 26 million tonnes of plastic scrap is generated in Europe every year. While traditional recycling efforts play a crucial role, not all of this ...
- You Can’t Tell, But I’m Wearing a Mineral Sunscreen in This Photoon May 7, 2024 at 5:00 pm
It requires fewer reapplications and is gentler on sensitive eyes; often, when I applied chemical sunscreen (my go-to was Unseen Sunscreen from Supergoop), I wound up in an endless loop of eye ...
- EPA, DEQ investigating unknown red substance in ditches following Perrydale barn fireon May 7, 2024 at 12:23 pm
The three-alarm fire took place at 7560 Perrydale Loop in the unincorporated community of Perrydale in Polk County. The property has an Amity address. Discolored water has since been flowing from the ...
- Loop Industries, Ester enter JV for India production facilityon May 7, 2024 at 7:09 am
Clean tech firm Loop Industries has entered a joint venture with Ester Industries to build and operate an Infinite Loop India manufacturing facility for the production of recycled dimethyl ...
- Loop Industries, Ester Industries form plastic recycling joint ventureon May 6, 2024 at 9:31 am
Loop Industries Inc., a Montreal-based recycler of polyethylene terephthalate (PET) and polyester fiber, has announced an agreement with India-based polyester film and specialty polymer producer Ester ...
- FDA misses own deadline to propose ban on cancer-linked formaldehyde from hair relaxerson May 2, 2024 at 4:41 pm
A proposal to ban formaldehyde in hair-straightening products that was scheduled to take place in April has not been released by the Food and Drug Administration, disregarding the agency’s own ...
- Loop partners with Ester on recycled polyester planton May 2, 2024 at 4:10 am
MONTREAL – Loop Industries, which offers technology that can chemically recycle low-grade polyester infinitely, has signed a joint venture agreement with polymer manufacturer Ester Industries to build ...
- US says Russia used choking agents against Ukrainian troops, breaching chemical weapons banon May 1, 2024 at 9:58 pm
Chloropicrin was widely used as a chemical warfare agent in World War I, but is no longer authorized for military use, and is now mostly used in agriculture, according to the CDC. It irritates the ...
- Loop Industries and Ester Industries Ltd. Announce Joint Venture Agreement to Build an Infinite Loop(TM) Manufacturing Facility in Indiaon May 1, 2024 at 5:00 pm
offering chemical companies a simple drop-in supplement and circular alternative that helps them achieve their sustainability goals. The rDMT and rMEG product offerings manufactured at the Infinite ...
- A state of emergency in Ontario’s Chemical Valleyon May 1, 2024 at 1:48 pm
Aamjiwnaang First Nation took the extreme measure after spikes in carcinogenic benzene were measured in the air during a plastics factory’s temporary shutdown ...
via Google News and Bing News