High Efficiency Achieved for Harvesting Hydrogen Fuel From the Sun using Earth-Abundant Materials

Oxygen and hydrogen bubbles forming on low-cost NiFe catalysts. ©Alain Herzog
Oxygen and hydrogen bubbles forming on low-cost NiFe catalysts. Credit: Alain Herzog
Today, the journal Science published the latest development in Michael Grätzel’s laboratory at EPFL: producing hydrogen fuel from sunlight and water.

By combining a pair of solar cells made with a mineral called perovskite and low cost electrodes, scientists have obtained a 12.3 percent conversion efficiency from solar energy to hydrogen, a record using earth-abundant materials as opposed to rare metals.

The race is on to optimize solar energy’s performance. More efficient silicon photovoltaic panels, dye-sensitized solar cells, concentrated cells and thermodynamic solar plants all pursue the same goal: to produce a maximum amount of electrons from sunlight. Those electrons can then be converted into electricity to turn on lights and power your refrigerator.

At the Laboratory of Photonics and Interfaces at EPFL, led by Michael Grätzel, where scientists invented dye solar cells that mimic photosynthesis in plants, they have also developed methods for generating fuels such as hydrogen through solar water splitting. To do this, they either use photoelectrochemical cells that directly split water into hydrogen and oxygen when exposed to sunlight, or they combine electricity-generating cells with an electrolyzer that separates the water molecules.

By using the latter technique, Grätzel’s post-doctoral student Jingshan Luo and his colleagues were able to obtain a performance so spectacular that their achievement is being published today in the journal Science. Their device converts into hydrogen 12.3 percent of the energy diffused by the sun on perovskite absorbers – a compound that can be obtained in the laboratory from common materials, such as those used in conventional car batteries, eliminating the need for rare-earth metals in the production of usable hydrogen fuel.[MW1]

Bottled sun

This high efficiency provides stiff competition for other techniques used to convert solar energy. But this method has several advantages over others:

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