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“Wetting” a battery’s appetite for renewable energy storage

“Wetting” a battery’s appetite for renewable energy storage

The traditional design of sodium-beta batteries, which uses pure molten sodium for a negative electrode, can be inefficient, as the sodium tends to ball up on the surface of the battery’s ceramic electrolyte, as shown on the left. PNNL researchers developed a new negative electrode made of a sodium-cesium alloy that almost completely coats, or “wets,” the electrolyte surface, as shown on the right.
The traditional design of sodium-beta batteries, which uses pure molten sodium for a negative electrode, can be inefficient, as the sodium tends to ball up on the surface of the battery’s ceramic electrolyte, as shown on the left. PNNL researchers developed a new negative electrode made of a sodium-cesium alloy that almost completely coats, or “wets,” the electrolyte surface, as shown on the right.
“Running at lower temperatures can make a big difference for sodium-beta batteries and may enable batteries to store more renewable energy and strengthen the power grid”

New liquid alloy electrode improves sodium-beta battery performance

Sun, wind and other renewable energy sources could make up a larger portion of the electricity America consumes if better batteries could be built to store the intermittent energy for cloudy, windless days. Now a new material could allow more utilities to store large amounts of renewable energy and make the nation’s power system more reliable and resilient.

A paper published today in Nature Communications describes an electrode made of a liquid metal alloy that enables sodium-beta batteries to operate at significantly lower temperatures. The new electrode enables sodium-beta batteries to last longer, helps streamline their manufacturing process and reduces the risk of accidental fire.

“Running at lower temperatures can make a big difference for sodium-beta batteries and may enable batteries to store more renewable energy and strengthen the power grid,” said material scientist Xiaochuan Lu of the Department of Energy’s Pacific Northwest National Laboratory.

Need for energy storage, but challenges remain

More than 300 megawatts of large, cargo container-sized sodium-beta batteries are running in the United States, Japan and Europe,according to Dupont Energy Consulting. They often store electricity generated by rows of solar panels and wind turbines.

But their broader use has been limited because of their high operating temperature, which reaches up to 350 degrees Celsius, or more than three times the boiling point of water. Such high operating temperatures requires sodium-beta batteries to use more expensive materials and shortens their operating lifespans. PNNL researchers set out to reduce the battery’s operating temperature, knowing that could make the battery more efficient and last longer.

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