This crystal of iron pyrite shows the characteristic cubic crystals of “fool’s gold.” A new study led by Song Jin at the University of Wisconsin-Madison identifies defects in pyrite’s crystal structure as a critical obstacle to building commercial solar cells from the cheap and abundant iron pyrite material.
As the installation of photovoltaic solar cells continues to accelerate, scientists are looking for inexpensive materials beyond the traditional silicon that can efficiently convert sunlight into electricity.
Theoretically, iron pyrite — a cheap compound that makes a common mineral known as fool’s gold — could do the job, but when it works at all, the conversion efficiency remains frustratingly low. Now, a University of Wisconsin-Madison research team explains why that is, in a discovery that suggests how improvements in this promising material could lead to inexpensive yet efficient solar cells.
“We think we now understand why pyrite hasn’t worked,” says chemistry Professor Song Jin, “and that provides the hope, based on our understanding, for figuring out how to make it work. This could be even more difficult, but exciting and rewarding.”
Although most commercial photovoltaic cells nowadays are based on silicon, the light-collecting film must be relatively thick and pure, which makes the production process costly and energy-intensive, says Jin.
A film of iron pyrite — a compound built of iron and sulfur atoms — could be 1,000 times thinner than silicon and still efficiently absorb sunlight.
Like silicon, iron and sulfur are common elements in the Earth’s crust, so solar cells made of iron pyrite could have a significant material cost advantage in large scale deployment. In fact, previous research that balanced factors like theoretical efficiency, materials availability, and extraction cost put iron pyrite at the top of the list of candidates for low-cost and large-scale photovoltaic materials.
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The Latest on: Iron pyrite
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