Graphene paints a corrosion-free future

Dr Nair with a graphene membrane
Dr Nair with a graphene membrane
A thin layer of graphene paint can make impermeable and chemically resistant coatings which could be used for packaging to keep food fresh for longer and protect metal structures against corrosion, new findings from The University of Manchester show.

The surface of graphene, a one atom thick sheet of carbon, can be randomly decorated with oxygen to create graphene oxide; a form of graphene that could have a significant impact on the chemical, pharmaceutical and electronic industries. Applied as paint, it could provide an ultra-strong, non-corrosive coating for a wide range of industrial applications.

Graphene oxide solutions can be used to paint various surfaces ranging from glass to metals to even conventional bricks. After a simple chemical treatment, the resulting coatings behave like graphite in terms of chemical and thermal stability but become mechanically nearly as tough as graphene, the strongest material known to man.

The team led by Dr Rahul Nair and Nobel laureate Sir Andre Geim demonstrated previously that multilayer films made from graphene oxide are vacuum tight under dry conditions but, if expose to water or its vapour, act as molecular sieves allowing passage of small molecules below a certain size. Those findings could have huge implications for water purification.

This contrasting property is due to the structure of graphene oxide films that consist of millions of small flakes stacked randomly on top of each other but leave nano-sized capillaries between them. Water molecules like to be inside these nanocapillaries and can drag small atoms and molecules along.

In an article published in Nature Communications this week, the University of Manchester team shows that it is possible to tightly close those nanocapillaries using simple chemical treatments, which makes graphene films even stronger mechanically as well as completely impermeable to everything: gases, liquids or strong chemicals. For example, the researchers demonstrate that glassware or copper plates covered with graphene paint can be used as containers for strongly corrosive acids.

The exceptional barrier properties of graphene paint have already attracted interest from many companies who now collaborate with The University of Manchester on development of new protective and anticorrosion coatings.

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