via Cornell University
Styrofoam egg cartons, hard plastic compact disc cases, red drinking cups and many other common products are composed of polystyrene, a type of plastic that makes up a third of landfill waste worldwide.
“In terms of plastic production and end-of-life waste streams, we are on the road to an unsustainable future,” said Erin Stache, assistant professor of chemistry and chemical biology in the College of Arts and Sciences.
But there’s good news: Stache has discovered a new path for polystyrene waste that includes being upcycled into benzoic acid, a chemical with wide commercial demand, through a mild process that uses light, an oxygen-rich environment and an abundant iron-based catalyst. The reaction can even take place in a sunny window.
The paper, “Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation” published March 23 in the Journal of the American Chemical Society. Doctoral candidate Sewon Oh is the lead author.
In line with her lab’s mission to tackle environmental concerns through interesting chemistry, the new process is mild, climate-friendly and scalable to commercial waste streams, Stache said. It efficiently produces benzoic acid, a product stocked in undergraduate and high school chemistry labs and also used in fragrances, food preservatives, and other ubiquitous products.
Moreover, the process is tolerant of additives inherent in a flow of consumer waste, including dirt, dyes and other types of plastics.
Polystyrene (PS) plastics vary widely in form, use and texture – from light, airy Styrofoam to hard CD cases, and many forms in between. All these products are similar in chemical composition, Stache said.
“The difference is in how they are processed,” she said. “Polystyrene foam, or Styrofoam, is filled with air, like a meringue, whereas a hard plastic CD case is solid polystyrene.”
At the molecular level, polymers (plastics) are composed of hundreds of small molecules called monomers assembled into long molecular chains through complicated processes, Stache said. Breaking down a polymer can be similarly intricate.
The researchers found that optimized conditions require a PS sample in acetone exposed to LED light in an oxygen-rich environment, using an iron chloride catalyst for 20 hours. In the optimized process, PS broke down to 23% benzoic acid. Other products included smaller plastic molecules that can be repurposed in other ways.
Last summer, Stache’s lab ran some degradation experiments in a sunny window; in a place with strong year-round sunlight, the reaction could be done outdoors.
“The advantage of using light is you can get exquisite control over the chemical process based on some of the catalysts we’ve developed to harness the white light. If we can use sunlight to drive the process, that’s a win-win,” Stache said, noting that many existing polymer recycling require heating a polymer for melting and processing, which usually requires fossil fuel.
To test the tolerance of the process to other materials mixed with the PS plastic, the researchers used several products, ranging from packaging materials to coffee cup lids.
They found that three items – a white coffee cup lid, Styrofoam and a clear lid – degraded efficiently. A black coffee cup lid degraded less efficiently, possibly because the black dyes inhibit light penetration, Stache said.
“These results signify that our system could efficiently break down commercial samples of PS, even with additional composite and insoluble material,” she said.
To demonstrate scalability and potential commercial application, the researchers created a setup with two syringe pumps and two LED lamps in a 3D-printed photoreactor. The efficiency of the breakdown process at the large scale was similar to that in small batches.
“If we can make the process even more efficient, we can think about how to commercialize it and use it to address waste streams,” Stache said.
Original Article: Light, oxygen turn waste plastics into useful benzoic acid
More from: Cornell University
The Latest Updates from Bing News & Google News
Go deeper with Bing News on:
Polystyrene waste
- UK government introduces simpler bin collections to boost recycling
U K Recycling Minister Robbie Moore has announced the introduction of a simpler recycling collection to boost recycling rates in England. The announcement was made on 9 May 2024. This initiative is ...
- Mechanical reclaim of XPS food trays successful in test / SCS develops circular design guideline
Our website uses cookies. Some of them are needed for the website to function properly, while others help us to improve the website to meet your needs. You will find further information in our privacy ...
- SAB prepares for the polystyrene ban
Colorado Senate Bill 19-243 went into effect prohibiting food establishments from distributing polystyrene foam containers and cups. The Nederland Sustainability Advisory Board (SAB) was called to ...
- Specialty Polystyrene Resin Market Set to Reach USD 195 Million by 2034 with 3.70% CAGR
The global specialty polystyrene resin market value is expected to rise from USD 135 million in 2024 to USD 195 million by 2034. This estimated growth is expected to be driven by a consistent CAGR of ...
- Taco Bell and TerraCycle Make Recycling Saucier
Their expanded recycling program for single-serving condiments targets rigid packs as well as flexible packaging.
Go deeper with Google Headlines on:
Polystyrene waste
[google_news title=”” keyword=”polystyrene waste” num_posts=”5″ blurb_length=”0″ show_thumb=”left”]
Go deeper with Bing News on:
Upcycling polystyrene waste
- Turning trash into treasure: breakthrough innovations in PET plastic upcycling
A recent review has unveiled revolutionary methods to recycle and transform everyday polyethylene terephthalate (PET) plastic into valuable materials.
- Scientists explore nature’s promise in combating plastic waste
By Claire Asher Plastic is a remarkably versatile and durable material, which has made it indispensable in almost every area of modern life. But these same properties, amplified by our ...
- Ethiopian plastic upcycling startup Kubik gets fresh funding, plans to license out its tech
Kubik, a plastic upcycling startup, has raised a $1.9 million seed extension, months after announcing initial equity investment. The startup’s latest investment is from African Renaissance Partners, ...
- Aqua Employees beautify Busse Woods; collect plastic waste for Upcycling Program
In addition to the park clean-up, Aqua employees also collected pliable plastic bags and film throughout the month as part of the nonprofit’s plastic bag recycling program, which transforms this ...
- Ethiopian plastic upcycling startup Kubik gets fresh funding, plans to license out its tech
Kubik’s approach involves upcycling plastic waste into “low-carbon, durable, and affordable” building materials using proprietary technology, which Asfaw says they will out-license for ...
Go deeper with Google Headlines on:
Upcycling polystyrene waste
[google_news title=”” keyword=”upcycling polystyrene waste” num_posts=”5″ blurb_length=”0″ show_thumb=”left”]