Dr Tony Shien-Ping Feng of the Department of Mechanical Engineering at the University of Hong Kong (HKU) and his team invented a Direct Thermal Charging Cell (DTCC) which can effectively convert heat to electricity, creating a huge potential to reduce greenhouse effects by capturing exhaust heat and cutting down primary energy wastage.
The new invention is recently published in the prestigious journal Nature Communications (http://www.i-nanoeng.com/upload/2019/09/20190918160051.pdf), and the research has been featured in the Nature Communications Editors’ Highlights webpage. HKU’s Technology Transfer Office has filed for the invention’s US provisional patent and PCT (Patent Cooperation Treaty) patent.
Low grade heat is abundantly available in industrial processes (80 to 150°C), as well as in the environment, living things, solar-thermal (50 to 60°C) and geothermal energy. Over 60% of the world’s primary energy input, whether it is in the industrial process or domestic energy consumption, is wasted as heat. A majority of this loss as waste heat is regarded as low-grade heat.
The newly designed DTCC is a game-changing electrochemical technology which can open new horizons for applications to convert low-grade heat to electricity efficiently. It is a simple system with the basic unit sized only 1.5 sq.cm and thickness 1 to 1.5 mm. The cell is bendable, stackable and low cost.
DTCC can be used in HVAC (heating, ventilation, and air conditioning) system to recycle low-grade heat from the compressor and condenser into electricity for use in electrical devices. It can be integrated with the window frame to harvest solar thermal energy to power electrochromic windows, or used as portable devices to power iphones or life-saving equipment in the wilderness. With the increasing popularity of wearable technology, this system may one day harness body heat to power wearable electronic devices or medical devices for monitoring body health conditions like blood sugar levels and blood pressure.
Dr Feng said: “Efficient low-grade heat recovery can help to reduce greenhouse gas emission but current technologies to convert this heat to electricity is still far from optimum. DTCC yields a conversion efficiency of over 3.5%, surpassing all existing thermo-electrochemical and thermo-electric systems, which is either too costly or complicated, or too low in efficiency for everyday applications. DTCC is a revolutionary design with great potentials in smart and sustainable energy devices.”
The new thermal charging cell uses asymmetric electrodes: a graphene oxide/platinum (GO/Pt) cathode and a polyaniline (PANI) anode in Fe2+/Fe3+ redox electrolyte via isothermal heating operation without building thermal gradient or thermal cycle. When heated, the cell generates voltage via a thermo-pseudocapacitive effect of GO and then discharges continuously by oxidizing the PANI anode and reducing Fe3+ to Fe2+ under isothermal heating on cathode side till Fe3+ depletion. The energy conversion works continuously under isothermal heating during the entire charge and discharge process. The system can be self-regenerated when cooled down. This synergistic chemical regeneration mechanism allows the device cyclability.
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