
Combining fundamental chemistry with high-performance computing resources at ORNL, researchers demonstrate a more efficient method for recovering uranium from seawater, unveiling a prototype material that outperforms best-in-class uranium adsorbents. Credit: Alexander Ivanov/Oak Ridge National Laboratory, U.S. Dept. of Energy.
Scientists have demonstrated a new bio-inspired material for an eco-friendly and cost-effective approach to recovering uranium from seawater.
A research team from the Department of Energy’s Oak Ridge and Lawrence Berkeley National Laboratories, the University of California, Berkeley, and the University of South Florida developed a material that selectively binds dissolved uranium with a low-cost polymer adsorbent. The results, published in Nature Communications, could help push past bottlenecks in the cost and efficiency of extracting uranium resources from oceans for sustainable energy production.
“Our approach is a significant leap forward,” said coauthor Ilja Popovs of ORNL’s Chemical Sciences Division. “Our material is tailor-made for selecting uranium over other metals present in seawater and can easily be recycled for reuse, making it much more practical and efficient than previously developed adsorbents.”
Popovs took inspiration from the chemistry of iron-hungry microorganisms. Microbes such as bacteria and fungi secret natural compounds known as “siderophores” to siphon essential nutrients like iron from their hosts. “We essentially created an artificial siderophore to improve the way materials select and bind uranium,” he said.
The team used computational and experimental methods to develop a novel functional group known as “H2BHT”—2,6-bis[hydroxy(methyl)amino]-4-morpholino-1,3,5-triazine—that preferentially selects uranyl ions, or water-soluble uranium, over competing metal ions from other elements in seawater, such as vanadium.
The fundamental discovery is backed by the promising performance of a proof-of-principle H2BHT polymer adsorbent. Uranyl ions are readily “adsorbed,” or bonded to the surface of the material’s fibers because of the unique chemistry of H2BHT. The prototype stands out among other synthetic materials for increasing the storage space for uranium, yielding a highly selective and recyclable material that recovers uranium more efficiently than previous methods.
With a practical recovery method, saltwater extraction offers a sustainable alternative to land-mining uranium that could sustain nuclear power production for millennia.
Uranium deposits are abundant and replenishable in seawater through the natural erosion of ore-containing rocks and soil. Despite dilute concentrations, approximately 3 milligrams of uranium per ton of seawater, the world’s oceans hold massive stores of the element totaling an estimated four billion tons—a 1000 times greater supply than all land sources combined.
The development of efficient uranium adsorbents to harness this potential resource, however, has been an elusive quest since the 1960s.
“The goal is to develop efficient adsorbent materials at a low cost that can be processed using mild conditions to recover uranium, and also reused for multiple extraction cycles,” said ORNL’s Alexander Ivanov, who performed computational studies of H2BHT.
Supported by the DOE Office of Nuclear Energy’s Fuel Cycle Research and Development program, the team has focused on determining the underlying factors that influence selectivity and increase the volume of recoverable uranium with new materials.
Previous studies on amidoxime-based compounds revealed a fundamentally stronger attraction to vanadium over uranium that may be difficult to overcome. The development of H2BHT offers an alternative approach, using non-amidoxime materials, to better target uranium in mixed-metal water environments.
Selectivity has long been a stumbling block on the road to more efficient adsorbent materials. Early advances, driven by trial and error, found amidoxime-based functional groups effectively bind uranium in water but do an even better job of recovering vanadium, although the latter has a comparatively lower concentration in seawater.
“The result is that amidoxime-based materials, the current front-runners for commercially available adsorbents, fill up more quickly with vanadium than uranium, which is difficult and costly to remove,” said Popovs.
The highly concentrated acidic solutions used to remove vanadium are an increased expense compared with mild or basic processing solutions and are burdened by caustic waste streams. Moreover, acid processing can damage material fibers, which limits their reuse, making commercial adoption cost-prohibitive.
“To work as a scaled-up concept, ideally, unwanted elements would not be adsorbed or could easily be stripped during processing and the material reused for several cycles to maximize the amount of uranium collected,” said Popovs.
Unlike vanadium-laden materials, the H2BHT polymer can be processed using mild basic solutions and recycled for extended reuse. The eco-friendly features also bring significant cost advantages to potential real-world applications.
The next step, say researchers, is to refine the approach for greater efficiency and commercial-scale opportunities. The journal article is published as “Siderophore-Inspired Chelator Hijacks Uranium from Aqueous Medium.”
Learn more: Bio-inspired material targets oceans’ uranium stores for sustainable nuclear energy
The Latest on: Recovering uranium from seawater
via Google News
The Latest on: Recovering uranium from seawater
- NEW EXPLOSION AT JAPAN'S FUKUSHIMA DAIICHI UNIT NO. 3 NUKE REACTORon January 8, 2021 at 4:00 pm
Officials had taken the unusual measure to cool the reactor with sea water, which means it's unlikely to be usable ... as a "partial meltdown" or "deformation" of at least one of the uranium fuel rods ...
- Indonesia’s Nuclear Dream, Revived?on December 31, 2020 at 10:27 pm
and some seawater experiments. Recent technological advancements have made it possible to recover uranium from different unconventional minerals. Indeed, Indonesia is very keen to develop ...
- Making The Case For Nuclear Aircrafton December 27, 2020 at 4:00 pm
Nuclear reactors use the controlled splitting of uranium atoms to produce energy. This energy is transferred into water as heat. The water is kept under high pressure, which keeps it from turning ...
- Global Uranium Supply and Demandon December 20, 2020 at 4:01 pm
Going forward, more global exploration to locate uranium--especially ore lower in cost to recover--is expected as long as market prices remain high. Some U.S. miners have expressed concern about ...
- Beyond power plants, nuclear tech has various peaceful applicationson December 19, 2020 at 4:09 pm
These include increasing crop yield with irrigation process and formula, extracting uranium from seawater and developing native fabrics for treating wastewater. He added that DOST-PNRI is looking ...
- Experts Divided Over Safety of Indian Point Nuclear Power Planton December 18, 2020 at 6:05 am
These spent rods along with the active uranium rods that power nuclear plants ... choosing to pump seawater into the reactors, Indian Point’s backup design offers a residual steam system to ...
- Recover uranium from seawater? D.O.S.T. nuke scientists doing studieson September 26, 2020 at 12:33 pm
Researchers worldwide are also studying this technology. Further, seawater uranium recovery technology is seen as a “game-changing approach.” The US government considers it as an area worthy ...
- Scientists extract uranium powder from seawateron August 14, 2018 at 7:29 am
Scientists say they have created five grams of yellowcake - a powdered form of uranium used to produce fuel for nuclear power production - using acrylic fibers to extract it from seawater.
- Erich Schneideron July 28, 2018 at 8:13 am
Schneider has consulted for the US Energy Department in multiple areas related to uranium, notably resources and production costs, uranium recovery from seawater, and depleted uranium management.
- Japan’s disaster toll rises with 18,000 deathson December 11, 2017 at 11:06 pm
Progress was made to reconnect two other units to the electric grid and in pumping seawater to cool another reactor and replenish ... “It is very distressing as we recover more bodies day by days,” ...
via Bing News