Splitting water into hydrogen and oxygen presents an alternative to fossil fuels, but purified water is a precious resource. A Stanford-led team has now developed a way to harness seawater – Earth’s most abundant source – for chemical energy.
Stanford researchers have devised a way to generate hydrogen fuel using solar power, electrodes and saltwater from San Francisco Bay.
The findings, published March 18 in Proceedings of the National Academy of Sciences, demonstrate a new way of separating hydrogen and oxygen gas from seawater via electricity. Existing water-splitting methods rely on highly purified water, which is a precious resource and costly to produce.
Theoretically, to power cities and cars, “you need so much hydrogen it is not conceivable to use purified water,” said Hongjie Dai, J.G. Jackson and C.J. Wood professor in chemistry in Stanford’s School of Humanities and Sciences and co-senior author on the paper. “We barely have enough water for our current needs in California.”
Hydrogen is an appealing option for fuel because it doesn’t emit carbon dioxide, Dai said. Burning hydrogen produces only water and should ease worsening climate change problems.
Dai said his lab showed proof-of-concept with a demo, but the researchers will leave it up to manufacturers to scale and mass produce the design.
As a concept, splitting water into hydrogen and oxygen with electricity – called electrolysis – is a simple and old idea: a power source connects to two electrodes placed in water. When power turns on, hydrogen gas bubbles out of the negative end – called the cathode – and breathable oxygen emerges at the positive end – the anode.
But negatively charged chloride in seawater salt can corrode the positive end, limiting the system’s lifespan. Dai and his team wanted to find a way to stop those seawater components from breaking down the submerged anodes.
The researchers discovered that if they coated the anode with layers that were rich in negative charges, the layers repelled chloride and slowed down the decay of the underlying metal.
They layered nickel-iron hydroxide on top of nickel sulfide, which covers a nickel foam core. The nickel foam acts as a conductor – transporting electricity from the power source – and the nickel-iron hydroxide sparks the electrolysis, separating water into oxygen and hydrogen. During electrolysis, the nickel sulfide evolves into a negatively charged layer that protects the anode. Just as the negative ends of two magnets push against one another, the negatively charged layer repels chloride and prevents it from reaching the core metal.
Without the negatively charged coating, the anode only works for around 12 hours in seawater, according to Michael Kenney, a graduate student in the Dai lab and co-lead author on the paper. “The whole electrode falls apart into a crumble,” Kenney said. “But with this layer, it is able to go more than a thousand hours.”
Previous studies attempting to split seawater for hydrogen fuel had run low amounts of electric current, because corrosion occurs at higher currents. But Dai, Kenney and their colleagues were able to conduct up to 10 times more electricity through their multi-layer device, which helps it generate hydrogen from seawater at a faster rate.
“I think we set a record on the current to split seawater,” Dai said.
The team members conducted most of their tests in controlled laboratory conditions, where they could regulate the amount of electricity entering the system. But they also designed a solar-powered demonstration machine that produced hydrogen and oxygen gas from seawater collected from San Francisco Bay.
And without the risk of corrosion from salts, the device matched current technologies that use purified water. “The impressive thing about this study was that we were able to operate at electrical currents that are the same as what is used in industry today,” Kenney said.
Looking back, Dai and Kenney can see the simplicity of their design. “If we had a crystal ball three years ago, it would have been done in a month,” Dai said. But now that the basic recipe is figured out for electrolysis with seawater, the new method will open doors for increasing the availability of hydrogen fuel powered by solar or wind energy.
In the future, the technology could be used for purposes beyond generating energy. Since the process also produces breathable oxygen, divers or submarines could bring devices into the ocean and generate oxygen down below without having to surface for air.
In terms of transferring the technology, “one could just use these elements in existing electrolyzer systems and that could be pretty quick,” Dai said. “It’s not like starting from zero – it’s more like starting from 80 or 90 percent.”
The Latest on: Hydrogen fuel from seawater
[google_news title=”” keyword=”hydrogen fuel from seawater” num_posts=”10″ blurb_length=”0″ show_thumb=”left”]
via Google News
The Latest on: Hydrogen fuel from seawater
- Clean Water And Solar Power In A Single Device: University Of Cambridge Team Creates Off-Grid Device To Purify Dirty Water And Produce Hydrogen Fuelon November 30, 2023 at 9:30 am
Developed by researchers at the University of Cambridge, the device can purify contaminated water or polluted seawater into clean drinking water and hydrogen fuel, a clean and sustainable energy ...
- Renewable hydrogen can drive net-zero industrial growth in developing countrieson November 27, 2023 at 8:15 am
The number of countries with national hydrogen roadmaps has more than tripled over the last two years. This shows that many states are getting ready to produce and use renewable hydrogen and benefit ...
- France Criticizes ‘Hydrogen Ready’ Plans for Gas Power Plantson November 27, 2023 at 6:48 am
France expressed doubts about proposals to keep building natural gas infrastructure such as power plants on the assumption that the fossil fuel will eventually be replaced with hydrogen.
- Hydrogen: A big piece of the clean-energy puzzleon November 26, 2023 at 4:01 pm
Hydrogen gas gets talked about a lot these days because it’s a clean alternative to natural gas. When burned as a fuel or used in a fuel cell, or used when it’s been converted to ammonia ...
- Could airports make hydrogen work as a fuel?on November 24, 2023 at 10:15 am
On a typical day 1,300 planes take off and land at Heathrow Airport, and keeping that going requires around 20 million litres of jet fuel every day. That's the equivalent of filling up your car around ...
- Could airports make hydrogen work as a fuel?on November 23, 2023 at 4:03 pm
So, there is much interest in hydrogen, which can store a lot of energy and, when used as fuel, does not produce any CO2. To be of any use to the aviation industry, hydrogen needs to be in its ...
- Innovative Solar-Powered Device Generates Clean Water and Fuel Simultaneouslyon November 22, 2023 at 4:00 pm
A floating, solar-powered device that can turn contaminated water or seawater into clean hydrogen fuel and purified water, anywhere in the world, has been developed by researchers. These are the sorts ...
- Sun-run device turns dirty water into hydrogen fuel & drinking wateron November 20, 2023 at 4:00 pm
solar-powered device that converts contaminated water or seawater into clean hydrogen fuel and drinking water. Because it works with any open water source and doesn’t require external power ...
- New stainless steel boosts green hydrogen production from seawateron November 19, 2023 at 10:04 am
its performance in a saltwater electrolyzer is equivalent to the present industrial practice of employing titanium as a key structural part to create hydrogen from desalted seawater or acid.
- This solar-powered device produces both clean water and clean energyon November 18, 2023 at 1:10 pm
A new solar-powered device capable of transforming contaminated water or seawater into clean hydrogen fuel and clean, drinkable water.
via Bing News