Aberration-corrected HAADF/STEM images of as-synthesized Rh-ZSM-5. Single rhodium cations are circled in white with proposed ball-stick model of the structure. (Lawrence F. Allard, co-author and researcher at Oak Ridge National Laboratory )
New process could lead to production of methanol or acetic acid through more energy efficient, low-cost and environmentally-friendly ways
The direct oxidation of methane—found in natural gas—into methanol at low temperatures has long been a holy grail. Now, researchers at Tufts have found a breakthrough way to accomplish the feat using a heterogeneous catalyst and cheap molecular oxygen, according to a paper published today in the journal Nature by a team led by Tufts University chemical engineers.
Methanol is a key feedstock for the production of chemicals, some of which are used to make products such as plastics, plywood and paints. Methanol also can fuel vehicles or be reformed to produce high-grade hydrogen for fuel cells.
However, the current method for producing methanol from methane- or coal-derived synthesis gas involves a multi-step process that is neither efficient nor economical in small-scale applications. As a result, methane emissions from oil wells, accounting for 210 billion cubic feet of natural gas annually, are being vented and flared, according to the U.S. Energy Information Administration. Meanwhile, the growth of hydraulic fracturing, or fracking, and the subsequent use of shale gas, the chief component of which is methane, have dramatically increased the natural gas supply in the United States, and accelerated the desire to upgrade methane into more valuable chemicals, such as through oxidation to methanol or carbonylation to acetic acid.
As a result, scientists have been seeking more efficient and less expensive ways to convert methane with a process that uses inexpensive molecular oxygen in mild conditions in which relatively low temperatures and pressures are used. The potential benefit is significant. In 2000, the availability of cheap shale gas represented just 1 percent of American natural gas supplies, while today it represents more than 60 percent.
The Tufts-led researchers found that they could use molecular oxygen and carbon monoxide for the direct conversion of methane to methanol catalyzed by supported mononuclear rhodium dicarbonyl species, anchored on the internal pore walls of zeolites or on the surface of titanium dioxide supports that were suspended in water under mild pressure (20 to 30 bar) and temperature (110 to 150° C).
The same catalyst also produces acetic acid through a different reaction scheme that does not involve methanol as an intermediate. Carbon monoxide is essential to the catalytic reaction, which is heterogeneous. Tuning the reaction to either methanol or acetic acid is possible by properly controlling the operating conditions, especially the acidity of the support. Even after many hours of reaction, there is no leaching of the catalyst in the water, the study found.
The paper’s senior author, Maria Flytzani-Stephanopoulos, Ph.D., a Distinguished Professor and the Robert and Marcy Haber Endowed Professor in Energy Sustainability in the School of Engineering at Tufts University, said the researchers were very surprised to find that carbon monoxide was necessary in the gas mixture to produce methanol.
“We attributed this to retaining the active site carbonylated,”Flytzani-Stephanopoulos said. “Interestingly, our catalyst does not carbonylate methanol. Instead, it carbonylates methane directly to acetic acid, which is a most exciting finding.”
“Although more study is needed, we are encouraged that this process holds promise for further development. Not only could it be effective in producing methanol and acetic acid directly from methane, it also could do so in a more energy efficient and environmentally friendly way than current processes,” she added.
Postdoctoral fellow JunJun Shan and doctoral student Mengwei Li, who are both first authors of the paper, prepared supported Rh catalysts through relatively simple synthesis procedures. The main focus was to atomically disperse the rhodium species, which was achieved by a special heat treatment protocol on the zeolite support and by anchoring rhodium precursor species on reduced titania assisted by UV-irradiation. The atomic rhodium state is necessary for the reaction to occur, said Shan.
Lawrence F. Allard, Ph.D., distinguished research staff member at Oak Ridge National Laboratory and a co-author of the paper, said aberration-corrected electron microscopy was crucial in supporting the research.
“The ‘direct’ imaging of single atom dispersions coupled with more standard ‘indirect’ chemical and spectroscopic methods has been a powerful combination of capabilities that allow these studies to be so successful,” Allard said.
Graph of U.S. natural gas gross withdrawals between 2000 and 2016 (Courtesy of Energy Information Administration)
Flytzani-Stephanopoulos directs the Tufts Nano Catalysis and Energy Laboratory, in the Department of Chemical and Biological Engineering, which investigates new catalyst materials for the production of hydrogen and “green” chemicals. Pioneering work from her lab has demonstrated the use of heterogeneous single metal atom catalysts for reactions of interest to fuel processing, and to commodity and value-added chemicals production, with improved yields and reduced carbon footprint, while using precious metals sustainably and more efficiently.
Learn more: Researchers discover breakthrough process for directly converting methane to methanol
The Latest on: Methane to methanol
- GLOBAL: ICCT: ‘Cruising is worse for the climate than flying’on May 17, 2022 at 4:06 am
‘Third, cruise companies should stop ordering LNG-powered cruise ships and instead start investing in ships that use non-methane alternative fuels, such as green methanol or even green hydrogen. One ...
- SunSirs: On May 16, the Chloroform Market Continued to Declineon May 16, 2022 at 8:30 pm
As of May 16, the price of raw material methanol of production enterprises was 2650 RMB/ton, and the cost side had support but weaker than the previous period.. In addition, the domestic methane ...
- Gas Technologies LLCon May 14, 2022 at 5:00 pm
GasTechno Says Methane-To-Methanol Plant Launch A SuccessGas Technologies LLC last week announced a successful launch of its first portable Portable Mini-GTL production plant in the field.
- METHANEX Releases 2021 Sustainability Reporton May 13, 2022 at 6:16 am
VANCOUVER, British Columbia, April 14, 2022 (GLOBE NEWSWIRE) -- Methanex Corporation (TSX:MX) (NASDAQ:MEOH), the world’s largest producer and supplier of methanol, released its 2021 Sustainability ...
- Walloon Lakeon May 12, 2022 at 5:00 pm
GasTechno Says Methane-To-Methanol Plant Launch A SuccessGas Technologies LLC last week announced a successful launch of its first portable Portable Mini-GTL production plant in the field.
- Clean Energy: Where India Stands In The Global Coal Gasification Marketon May 12, 2022 at 5:11 am
The Union Ministry of Coal (MoC) has allowed concession of 50 per cent in revenue share for coal gasification. This was stated by Union Minister of Coal, Mines and Parliamentary Affairs Pralhad Joshi ...
- Hokkaido town seeks to squeeze more methanol out of cow dungon May 4, 2022 at 5:01 pm
Methanol, a raw material in various chemical products, has a broader use than methane, derived from cattle dung, which is mostly used to generate electric power. The town government of Okoppe on ...
- Techno-economic analysis of renewables-driven power-to-X processeson April 29, 2022 at 12:15 am
Now, researchers at the University of Genoa have investigated and compared four green P2X solutions – hydrogen, methane, methanol, and ammonia – powered by various renewable energy sources in ...
- Methanex Reports Excellent First Quarter 2022 Resultson April 27, 2022 at 2:23 pm
Continued strong methanol pricing generated net income attributable to Methanex shareholders of $119 million and Adjusted EBITDA of $337 million. Methanol industry fundamentals remain solid ...
via Google News and Bing News