Smarter window materials can control light and energy

The illustration demonstrates the dark, bright and cool mode made possible by the researchers’ new architected nanocomposite. The team organized the two components of the composite material to create a porous interpenetrating network. This organization enables substantially faster switching between modes.
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Nano Letters

Researchers in the Cockrell School of Engineering at The University of Texas at Austin are one step closer to delivering smart windows with a new level of energy efficiency, engineering materials that allow windows to reveal light without transferring heat and, conversely, to block light while allowing heat transmission, as described in two new research papers.

By allowing indoor occupants to more precisely control the energy and sunlight passing through a window, the new materials could significantly reduce costs for heating and cooling buildings.

In 2013, chemical engineering professor Delia Milliron and her team became the first to develop dual-band electrochromic materials that blend two materials with distinct optical properties for selective control of visible and heat-producing near-infrared light (NIR). In a 2013 issue of Nature, Milliron’s research group demonstrated how, using a small jolt of electricity, a nanocrystal material could be switched back and forth, enabling independent control of light and energy.

The team now has engineered two new advancements in electrochromic materials — a highly selective cool mode and a warm mode — not thought possible several years ago.

The cool mode material is a major step toward a commercialized product because it enables control of 90 percent of NIR and 80 percent of the visible light from the sun and takes only minutes to switch between modes. The previously reported material could require hours.

To achieve this high performance, Milliron and a team, including Cockrell School postdoctoral researcher Jongwook Kim and collaborator Brett Helms of the Lawrence Berkeley National Lab, developed a new nanostructured architecture for electrochromic materials that allows for a cool mode to block near-infrared light while allowing the visible light to shine through. This could help reduce energy costs for cooling buildings and homes during the summer. The researchers reported the new architecture in Nano Letters on July 20.

“We believe our new architected nanocomposite could be seen as a model material, establishing the ideal design for a dual-band electrochromic material,” Milliron said. “This material could be ideal for application as a smart electrochromic window for buildings.”

In the paper, the team demonstrates how the new material can strongly and selectively modulate visible light and NIR by applying a small voltage.

To optimize the performance of electrochromics for practical use, the team organized the two components of the composite material to create a porous interpenetrating network. The framework architecture provides channels for transport of electronic and ionic change. This organization enables substantially faster switching between modes.

The researchers are now working to produce a similarly structured nanocomposite material by simple methods, suitable for low-cost manufacturing.

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