Reshaping the solar spectrum to turn light to electricity

Photographs of upconversion in a cuvette containing cadmium selenide/rubrene mixture. The yellow spot is emission from the rubrene originating from (a) an unfocused continuous wave 800 nm laser with an intensity of 300 W/cm2. (b) a focused continuous wave 980 nm laser with an intensity of 2000 W/cm2. The photographs, taken with an iPhone 5, were not modified in any way.
CREDIT
Zhiyuan Huang, UC Riverside.

UC Riverside researchers find a way to use the infrared region of the sun’s spectrum to make solar cells more efficient

When it comes to installing solar cells, labor cost and the cost of the land to house them constitute the bulk of the expense. The solar cells — made often of silicon or cadmium telluride — rarely cost more than 20 percent of the total cost. Solar energy could be made cheaper if less land had to be purchased to accommodate solar panels, best achieved if each solar cell could be coaxed to generate more power.

A huge gain in this direction has now been made by a team of chemists at the University of California, Riverside that has found an ingenious way to make solar energy conversion more efficient. The researchers report in Nano Letters that by combining inorganic semiconductor nanocrystals with organic molecules, they have succeeded in “upconverting” photons in the visible and near-infrared regions of the solar spectrum.

“The infrared region of the solar spectrum passes right through the photovoltaic materials that make up today’s solar cells,” explained Christopher Bardeen, a professor of chemistry. The research was a collaborative effort between him and Ming Lee Tang, an assistant professor of chemistry. “This is energy lost, no matter how good your solar cell. The hybrid material we have come up with first captures two infrared photons that would normally pass right through a solar cell without being converted to electricity, then adds their energies together to make one higher energy photon. This upconverted photon is readily absorbed by photovoltaic cells, generating electricity from light that normally would be wasted.”

Bardeen added that these materials are essentially “reshaping the solar spectrum” so that it better matches the photovoltaic materials used today in solar cells. The ability to utilize the infrared portion of the solar spectrum could boost solar photovoltaic efficiencies by 30 percent or more.

Read more: Reshaping the solar spectrum to turn light to electricity