Revving up fluorescence for superfast LEDs & quantum cryptography

This is an artist’s representation of light trapped between a silver nanocube and a thin sheet of gold. When fluorescent molecules — shown in red — are trapped between the two, they emit photons up to 1,000 times faster than normal.
Credit: Gleb Akselrod, Duke University

“If we can precisely place molecules like this, it could be used in many more applications than just fast LEDs,” said Akselrod. “We could also make fast sources of single photons that could be used for quantum cryptography. This technology would allow secure communication that could not be hacked — at least not without breaking the laws of physics.”

Duke University researchers have made fluorescent molecules emit photons of light 1,000 times faster than normal — setting a speed record and making an important step toward realizing superfast light emitting diodes (LEDs) and quantum cryptography.

This year’s Nobel Prize in physics was awarded for the discovery of how to make blue LEDs, allowing everything from more efficient light bulbs to video screens. While the discovery has had an enormous impact on lighting and displays, the slow speed with which LEDs can be turned on and off has limited their use as a light source in light-based telecommunications.

In an LED, atoms can be forced to emit roughly 10 million photons in the blink of an eye. Modern telecommunications systems, however, operate nearly a thousand times faster. To make future light-based communications using LEDs practical, researchers must get photon-emitting materials up to speed.

In a new study, engineers from Duke increased the photon emission rate of fluorescent molecules to record levels by sandwiching them between metal nanocubes and a gold film.

The results appear online October 12 in Nature Photonics.

“One of the applications we’re targeting with this research is ultrafast LEDs,” said Maiken Mikkelsen, an assistant professor of electrical and computer engineering and physics at Duke. “While future devices might not use this exact approach, the underlying physics will be crucial.”

Mikkelsen specializes in plasmonics, which studies the interaction between electromagnetic fields and free electrons in metal. In the experiment, her group manufactured 75-nanometer silver nanocubes and trapped light between them, greatly increasing the light’s intensity.

When fluorescent molecules are placed near intensified light, the molecules emit photons at a faster rate through an effect called Purcell enhancement. The researchers found they could achieve a significant speed improvement by placing fluorescent molecules in a gap between the nanocubes and a thin film of gold.

To attain the greatest effect, Mikkelsen’s team needed to tune the gap’s resonant frequency to match the color of light that the molecules respond to. With the help of co-author David R. Smith, the James B. Duke Professor and Chair of Electrical and Computer Engineering at Duke, they used computer simulations to determine the exact size of the gap needed between the nanocubes and gold film to optimize the setup.

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