Dyes help harvest visible and infrared light

Zinc porphyrin dyes were used to create solar cells that can absorb both visible and near-infrared light.
via: A*STAR Institute of Materials Research and Engineering

Dye-sensitized solar cell absorbs a broad range of visible and infrared wavelengths

Dye-sensitized solar cells (DSSCs) rely on dyes that absorb light to mobilize a current of electrons and are a promising source of clean energy. Jishan Wu at the A*STAR Institute of Materials Research and Engineering and colleagues in Singapore have now developed zinc porphyrin dyes that harvest light in both the visible and near-infrared parts of the spectrum1. Their research suggests that chemical modification of these dyes could enhance the energy output of DSSCs.

DSSCs are easier and cheaper to manufacture than conventional silicon solar cells, but they currently have a lower efficiency. Ruthenium-based dyes have been traditionally used in DSSCs, but in 2011 researchers developed a more efficient dye based on a zinc atom surrounded by a ring-shaped molecule called a porphyrin. Solar cells using this new dye, called YD2-o-C8, convert visible light into electricity with an efficiency of up to 12.3 per cent. Wu’s team aimed to improve that efficiency by developing a zinc porphyrin dye that can also absorb infrared light.

The most successful dyes developed by Wu’s team, WW-5 and WW-6, unite a zinc porphyrin core with a system of fused carbon rings bridged by a nitrogen atom, known as an N-annulated perylene group. Solar cells containing these dyes absorbed more infrared light than YD2-o-C8 and had efficiencies of up to 10.5 per cent, matching the performance of an YD2-o-C8 cell under the same testing conditions.

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